Would this work with pre populating fields from Volusion?

Would this work with pre populating fields from Volusion? It would be really awesome of some information was able to pull from my store.

As long as the data can be added to the form URL then yes, it would work.  Since I am not too familiar with Volusion and how data is passed or accessed when using it, I cannot give an example of how it would be done.  But as long as you can pass the data from Volusion to the form URL, it should work.