I want to connect 2 different emails to a free account.

I want to have 2 emails on a free account. I want each submission to go to these 2 email accounts. Can this be done?

Yes it's possible to use two separate email addresses for one of your jotforms.

There are two possible ways to do this.

One, you could just create two email notifications and have these sent separately to each of your email addresses. 

Two, alternatively you could just create one email notification with multiple email addresses.