JotForm is a free online form builder which helps you create online forms without writing a single line of code. No sign-up required.
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You can configure a notifier in your form in order to receive an email every time a submission is made in your form which can also include a PDF file attached to it with the submitted information.
You can also configure an autoresponder which would work in a similar way, but this would be to send a copy of the submitted data to the people that have completed your form.