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Yes that's very much possible.
You can add a dorp down question in your form and use our condition logic feature to send submission emails to different email address based on the drop down selection.
There is a guide already created which should help you understand how this works: http://www.jotform.com/help/167-How-to-send-to-a-specific-email-address-based-on-a-selection
Do let us know if you have more questions on this and we will be happy to assist you in implementing this in your form.