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When you are referring to "alpha order" did you mean Alphabetical Order or did you mean something else by that?
Yes this is possible. To do this select your Form then View its Submissions and scroll down to the bottom where they are listed and you can change the sorting function to "Ascending A-Z" then download it using the "Download as PDF" and you will see all of your downloaded submissions for your PDF are in Alphabetical Order. :)